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Title: Chemistry/Elements/Argon - Wikipedia: Argon Details the properties of the element, including its history, applications, and characteristics.
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Argon

From Wikipedia, the free encyclopedia Jump to: navigation, search This article is about the chemical element. For other uses, see Argon (disambiguation).18chlorine ← argon → potassiumNe↑Ar↓KrArgon in the periodic table of the elementsPeriodic table - Extended periodic tableGeneralName, symbol, numberargon, Ar, 18Element categorynoble gasesGroup, period, block18, 3, pAppearancecolourless gasStandard atomic weight39.950(1) g·mol−1Electron configuration[Ne] 3s2 3p6Electrons per shell2, 8, 8Physical propertiesPhasegasDensity(0 °C, 101.325 kPa)1.784 g/LMelting point83.80 K(−189.35 °C, −308.83 °F)Boiling point87.30 K(−185.85 °C, −302.53 °F)Triple point83.8058 K (-189°C), 69 kPaCritical point150.87 K, 4.898 MPaHeat of fusion1.18 kJ·mol−1Heat of vaporization6.43 kJ·mol−1Specific heat capacity(25 °C) 20.786 J·mol−1·K−1Vapor pressureP/Pa1101001 k10 k100 kat T/K 4753617187Atomic propertiesCrystal structurecubic face centeredOxidation states0Electronegativityno data (Pauling scale)Ionization energies(more)1st: 1520.6 kJ·mol−12nd: 2665.8 kJ·mol−13rd: 3931 kJ·mol−1Atomic radius71 pmAtomic radius (calc.)71 pmCovalent radius97 pmVan der Waals radius188 pmMiscellaneousMagnetic orderingnonmagneticThermal conductivity(300 K) 17.72x10-3  W·m−1·K−1Speed of sound(gas, 27 °C) 323 m/sCAS registry number7440–37–1Selected isotopesMain article: Isotopes of argonisoNAhalf-lifeDMDE (MeV)DP36Ar0.337%36Ar is stable with 18 neutrons37Arsyn35 dε0.81337Cl38Ar0.063%38Ar is stable with 20 neutrons39Arsyn269 yβ-0.56539K40Ar99.600%40Ar is stable with 22 neutrons41Arsyn109.34 minβ-2.4941K42Arsyn32.9 yβ-0.60042KReferencesThis box: view • talk • editArgon (pronounced /ˈɑrgɒn/) is a chemical element designated by the symbol Ar. Argon has atomic number 18 and is the third element in group 18 of the periodic table (noble gases). Argon is present in the Earth's atmosphere at 0.94%. Terrestrially, it is the most abundant and most frequently used of the noble gases. Argon's full outer shell makes it stable and resistant to bonding with other elements. Its triple point temperature of 83.8058 K is a defining fixed point in the International Temperature Scale of 1990.

Contents

1 Characteristics2 History3 Occurrence4 Isotopes5 Compounds6 Production6.1 Industrial6.2 In radioactive decays7 Applications8 Potential hazards9 References10 Further reading11 External links//

[edit] Characteristics

Argon has approximately the same solubility in water as oxygen gas and is 2.5 times more soluble in water than nitrogen gas. Argon is colorless, odorless, tasteless and nontoxic in both its liquid and gaseous forms. Argon is inert under most conditions and forms no confirmed stable compounds at room temperature.Although argon is a noble gas, it has been found to have the capability of forming some compounds. For example, the creation of argon hydrofluoride (HArF), a metastable compound of argon with fluorine and hydrogen, was reported by researchers at the University of Helsinki in 2000.[1] Although the neutral ground-state chemical compounds of argon are presently limited to HArF, argon can form clathrates with water when atoms of it are trapped in a lattice of the water molecules.[2] Also argon-containing ions and excited state complexes, such as ArH+ and ArF, respectively, are known to exist. Theoretical calculations have shown several argon compounds that should be stable but for which no synthesis routes are currently known.

[edit] History

Cavendish's method for the isolation of Argon. The gases are contained in a test-tube (A) standing over a large quantity of weak alkali (B), and the current is conveyed in wires insulated by U-shaped glass tubes (CC) passing through the liquid and rouind the mouth of the test-tube. The inner platinum ends (DD) of the wire receive a current from a battery of five Grove cells and a Ruhmkorff coil of medium size.Argon (Greek meaning "inactive," in reference to its chemical inactivity)[3][4][5] was suspected to be present in air by Henry Cavendish in 1785 but was not discovered until 1894 by Lord Rayleigh and Sir William Ramsay in Scotland in an experiment in which they removed all of the oxygen and nitrogen from a sample of air.[6][7] They had determined that nitrogen produced from chemical compounds was one-half percent lighter than nitrogen from the atmosphere. The difference seemed insignificant, but it was important enough to attract their attention for many months. They concluded that there was another gas in the air mixed in with the nitrogen.[8] Argon was also encountered in 1882 through independent research of H.F. Newall and W.N. Hartley. Each observed new lines in the color spectrum of air but were unable to identify the element responsible for the lines. Argon became the first member of the noble gases to be discovered. The symbol for argon is now Ar, but up until 1957 it was A.[9]

[edit] Occurrence

An argon & mercury vapour discharge tube.Argon constitutes 0.934% by volume and 1.29% by mass of the Earth's atmosphere, and air is the primary raw material used by industry to produce purified argon products. Argon is isolated from air by fractionation, most commonly by cryogenic fractional distillation, a process that also produces purified nitrogen, oxygen, neon, krypton and xenon.[10]The Martian atmosphere in contrast contains 1.6% of argon-40 and 5 ppm of argon-36. The Mariner spaceprobe fly-by of the planet Mercury in 1973 found that Mercury has a very thin atmosphere with 70% argon, believed to result from releases of the gas as a decay product from radioactive materials on the planet. In 2005, the Huygens probe also discovered the presence of argon-40 on Titan, the largest moon of Saturn.[11]

[edit] Isotopes

Main article: Isotopes of argonThe main isotopes of argon found on Earth are 40Ar (99.6%), 36Ar (0.34%), and 38Ar (0.06%). Naturally occurring 40K with a half-life of 1.25×109 years, decays to stable 40Ar (11.2%) by electron capture and positron emission, and also to stable 40Ca (88.8%) via beta decay. These properties and ratios are used to determine the age of rocks.[12]In the Earth's atmosphere, 39Ar is made by cosmic ray activity, primarily with 40Ar. In the subsurface environment, it is also produced through neutron capture by 39K or alpha emission by calcium. 37Ar is created from the decay of 40Ca as a result of subsurface nuclear explosions. It has a half-life of 35 days.[12]

[edit] Compounds

Argon’s complete octet of electrons indicates full s and p subshells. This full outer energy level makes argon very stable and extremely resistant to bonding with other elements. Before 1962, argon and the other noble gases were considered to be chemically inert and unable to form compounds; however, compounds of the heavier noble gases have since been synthesized. In August 2000, the first argon compounds were formed by researchers at the University of Helsinki. By shining ultraviolet light onto frozen argon containing a small amount of hydrogen fluoride, argon hydrofluoride (HArF) was formed.[13] It is stable up to 40 kelvins (−233 °C).See also: H2-ArA small piece of rapidly melting argon ice.

[edit] Production

[edit] IndustrialArgon is produced industrially by the partial distillation of liquid air, a process that separates liquid nitrogen, which boils at 77.3 K, from argon, which boils at 87.3 K and oxygen, which boils at 90.2 K. About 700,000 tons of argon are produced worldwide every year. [14][edit] In radioactive decaysArgon-40, the most abundant isotope of argon, is produced by the decay of potassium-40 with a half-life of 1.26×109 years by electron capture or positron emission. Because of this, it is used in potassium-argon dating to determine the age of rocks.

[edit] Applications

Cylinders containing argon gas for use in extinguishing fire without damaging server equipmentThere are several different reasons why argon is used in particular applications:An inert gas is needed. In particular, argon is the cheapest alternative when diatomic nitrogen is not sufficiently inert.Low thermal conductivity is required.The electronic properties (ionization and/or the emission spectrum) are necessary.Other noble gases would probably work as well in most of these applications, but argon is by far the cheapest. Argon is inexpensive since it is a byproduct of the production of liquid oxygen and liquid nitrogen, both of which are used on a large industrial scale. The other noble gases (except helium) are produced this way as well, but argon is the most plentiful since it has the highest concentration in the atmosphere. The bulk of argon applications arise simply because it is inert and relatively cheap. Argon is used:As a fill gas in incandescent lighting, because argon will not react with the filament of light bulbs even at high temperatures.As an inert gas shield in many forms of welding, including metal inert gas welding and tungsten inert gas welding. For metal inert gas welding argon is often mixed with CO2.For extinguishing fires where damage to equipment is to be avoided (see photo).As the gas of choice for the plasma used in ICP spectroscopy.As the gas of choice (in ionised form) for sputter coating of specimens for Scanning Electron Microscopy.As a non-reactive blanket in the processing of titanium and other reactive elements.As a protective atmosphere for growing silicon and germanium crystals, and in partial pressure heat treat furnaces.By museum conservators to protect old materials or documents, which are prone to gradual oxidation in the presence of air.[15]To keep open bottles of wine from oxidizing, and in a number of dispensing units and keeper cap systems.To preserve leftover finishes like varnish, polyurethane, paint, and other chemicals during storage. Commercially available in an aerosol can for this purpose (US Patent 6629402).In winemaking to top off barrels, displacing oxygen and thus preventing the wine from turning to vinegar during the aging process.In the pharmaceutical industry to top off bottles of intravenous drug preparations (for example intravenous paracetamol), again displacing oxygen and therefore prolonging the drug's shelf-life.Used to cool the seeker head of the US Air Force version of the AIM-9 Sidewinder missile, and other missiles that use cooled thermal seeker heads. The gas is stored at high pressure, and the expansion of the gas cools the seeker.[16]As an atmosphere in graphite electric furnaces, to keep graphite from oxidizing.As an asphyxiant in the poultry industry, either for mass culling following disease outbreaks, or as a means of slaughter more humane than the electric bath. Argon's relatively high density causes it to remain close to the ground during gassing. Its non-reactive nature makes it suitable in a food product, and since it replaces oxygen at a cellular level in the dead bird, argon also enhances shelf life.[17]As filling of vapour discharge tubes with blue colour .It is used for thermal insulation in energy efficient windows.[18] Argon is also used in technical scuba diving to inflate a dry suit, because it is inert and has low thermal conductivity.[19] It has also used experimentally to replace nitrogen in the breathing or decompression mix, to speed the elimination of dissolved nitrogen from the blood.[20] See Argox (scuba).Argon is also used for the specific way it ionizes and emits light. It is used in plasma globes and calorimetry in experimental particle physics. Blue argon lasers are used in surgery to weld arteries, destroy tumors, and to correct eye defects.[21] In microelectronics, argon ions are used for sputtering.Finally, there are a number of miscellaneous uses. Argon-39, with a half life of 269 years, has been used for a number of applications, primarily ice core and ground water dating. Also, potassium-argon dating is used in dating igneous rocks.Cryosurgery procedures such as cryoablation use liquified argon to destroy cancer cells. In surgery it is used in a procedure called "argon enhanced coagulation" which is a form of argon plasma beam electrosurgery. The procedure carries a risk of producing gas embolism in the patient and has resulted in the death of one person via this type of accident.[22]

[edit] Potential hazards

Please help improve this section by expanding it. Further information might be found on the talk page. (January 2008)Although argon is non-toxic, it does not satisfy the body's need for oxygen and is thus a simple asphyxiant, and, in confined spaces, is known to result in death due to asphyxiation. A recent fatality in Alaska highlights the dangers of argon tank leakage in confined spaces, and emphasizes the need for proper use, storage and handling. Argon is also odorless, tasteless, and colorless, making it hard to perceive.[23] Argon is 25% heavier than air and thus it is considered highly dangerous in closed areas.

[edit] References

^ "Periodic Table of the Elements: Argon." Lenntech. 2008. Retrieved on September 3, 2007.^ Belosludov, V. R.; O. S. Subbotin, D. S. Krupskii, O. V. Prokuda, and Y. Kawazoe (2006). "Microscopic model of clathrate compounds" (pdf) 1. Institute of Physics (has blown up once in a while) Publishing. Retrieved on 2007-03-08.^ Hiebert, E. N. Historical Remarks on the Discovery of Argon: The First Noble Gas. In Noble-Gas Compounds; Hyman, H. H., Ed.; University of Chicago Press: Chicago, IL, 1963; pp 3–20.^ Travers, M. W. The Discovery of the Rare Gases; Edward Arnold & Co.: London, 1928; pp 1–7.^ Rayleigh, Lord; Ramsay, W. Argon: A New Constituent of the Atmosphere. Chem. News 1895 (February 1), 71, 51–58.^ Lord Rayleigh;William Ramsay (1894 - 1895). "Argon, a New Constituent of the Atmosphere". Proceedings of the Royal Society of London 57 (1): 265–287. doi:10.1098/rspl.1894.0149. http://links.jstor.org/sici?sici=0370-1662%281894%2F1895%2957%3C265%3AAANCOT%3E2.0.CO%3B2-X. ^ William Ramsay. "Nobel Lecture in Chemistry, 1904".^ ABOUT ARGON, THE INERT; The New Element Supposedly Found in the Atmosphere. The New York Times, 3 March 1895^ Holden, Norman E. (12). "History of the Origin of the Chemical Elements and Their Discoverers". National Nuclear Data Center (NNDC).^ "Argon, Ar". Retrieved on 2007-03-08.^ "Seeing, touching and smelling the extraordinarily Earth-like world of Titan". European Space Agency (21).^ a b "40Ar/39Ar dating and errors". Retrieved on 2007-03-07.^ Bartlett, Neil. "The Noble Gases". Chemical & Engineering News.^ "Periodic Table of Elements: Argon – Ar (EnvironmentalChemistry.com)<!- Bot generated title ->". Environmentalchemistry.com. Retrieved on 2008-09-12.^ USA National Archives description of how the Declaration of Independence is stored and displayed. More detail can be found in this more technical explanation, especially Page 4, which talks about the argon keeping the oxygen out.^ Description of Aim-9 Operation^ ""Humane" Poultry Slaughter: Humane Slaughter: Animal Rights vs. Animal Welfare - Downbound.com". Downbound.com. Retrieved on 2008-09-12.^ "Energy-Efficient Windows". Bc Hydro. Retrieved on 2007-03-08.^ Nuckols, Marshall L; Giblo, J; Wood-Putnam, JL (2008). "Thermal characteristics of diving garments when using argon as a suit inflation gas (abstract)". Undersea and Hyperbaric Medicine 35 (4). http://archive.rubicon-foundation.org/7789. Retrieved on 24 October 2008. ^ Pilmanis Andrew A, Balldin UI, Webb James T, Krause KM (December 2003). "Staged decompression to 3.5 psi using argon-oxygen and 100% oxygen breathing mixtures". Aviation, Space, Environmental Medicine 74 (12): 1243–50. PMID 14692466. http://www.ingentaconnect.com/content/asma/asem/2003/00000074/00000012/art00004. Retrieved on 24 October 2008. ^ Fujimoto, James; Rox Anderson, R. (2006). "Tissue Optics, Laser-Tissue Interaction, and Tissue Engineering" 77-88. Biomedical Optics. Retrieved on 2007-03-08.^ "Fatal Gas Embolism Caused by Overpressurization during Laparoscopic Use of Argon Enhanced Coagulation". MDSR (24).^ Middaugh, John; Bledsoe, Gary. "Welder's Helper Asphyxiated in Argon-Inerted Pipe (FACE AK-94-012)." State of Alaska Department of Public Health. June 23, 1994. Retrieved on September 3, 2007.

[edit] Further reading

Los Alamos National Laboratory – ArgonUSGS Periodic Table - ArgonEmsley, J., Nature’s Building Blocks; Oxford University Press: Oxford, NY, 2001; pp. 35-39.Brown, T. L.; Bursten, B. E.; LeMay, H. E., In Chemistry: The Central Science, 10th ed.; Challice, J.; Draper, P.; Folchetti, N. et al.; Eds.; Pearson Education, Inc.: Upper Saddle River, NJ, 2006; pp. 276 and 289.Triple point temperature: 83.8058 K - Preston-Thomas, H. (1990). "The International Temperature Scale of 1990 (ITS-90)". Metrologia 27: 3–10. doi:10.1088/0026-1394/27/1/002. http://www.bipm.org/en/publications/its-90.html. Triple point pressure: 69 kPa - "Section 4, Properties of the Elements and Inorganic Compounds; Melting, boiling, triple, and critical temperatures of the elements". CRC Handbook of Chemistry and Physics (85th edition ed.). Boca Raton, Florida: CRC Press. 2005. 

[edit] External links

Sister projectWikimedia Commons has media related to: ArgonSister projectLook up argon inWiktionary, the free dictionary.WebElements.com – ArgonDiving applications: Why Argon?Argon Ar Properties, Uses, ApplicationsLeftover Finish Preserver – Bloxygenv • d • eE numbersColors (E100–199) • Preservatives (E200–299) • Antioxidants & Acidity regulators (E300–399) • Thickeners, stabilisers & emulsifiers (E400–499) • pH regulators & anti-caking agents (E500–599) • Flavour enhancers (E600–699) • Miscellaneous (E900–999) • Additional chemicals (E1100–1599)Waxes (E900–909) • Synthetic glazes (E910–919) • Improving agents (E920–929) • Packaging gases (E930–949) • Sweeteners (E950–969) • Foaming agents (E990–999)Calcium peroxide (E930) • Argon (E938) • Helium (E939) • Dichlorodifluoromethane (E940) • Nitrogen (E941) • Nitrous oxide (E942) • Butane (E943a) • Isobutane (E943b) • Propane (E944) • Oxygen (E948) • Hydrogen (E949)v • d • ePeriodic tableH HeLiBe BCNOFNeNaMg AlSiPSClArKCa ScTiVCrMnFeCoNiCuZnGaGeAsSeBrKrRbSr YZrNbMoTcRuRhPdAgCdInSnSbTeIXeCsBaLaCePrNdPmSmEuGdTbDyHoErTmYbLuHfTaWReOsIrPtAuHgTlPbBiPoAtRnFrRaAcThPaUNpPuAmCmBkCfEsFmMdNoLrRfDbSgBhHsMtDsRgUubUutUuqUupUuhUusUuo Alkali metalsAlkaline earth metalsLanthanoidsActinoidsTransition metalsOther metalsMetalloidsOther nonmetalsHalogensNoble gasesRetrieved from "http://en.wikipedia.org/wiki/Argon" Categories: Chemical elements | Noble gases | ArgonHidden categories: Articles to be expanded since January 2008 | All articles to be expanded Views Article Discussion Edit this page History Personal tools Log in / create account if (window.isMSIE55) fixalpha(); Navigation Main page Contents Featured content Current events Random article Search   Interaction About Wikipedia Community portal Recent changes Contact Wikipedia Donate to Wikipedia Help Toolbox What links here Related changesUpload fileSpecial pages Printable version Permanent linkCite this page Languages Afrikaans العربية Asturianu Azərbaycan বাংলা Беларуская Bosanski Български Català Чăвашла Česky Corsu Cymraeg Dansk Deutsch Eesti Ελληνικά Español Esperanto Euskara فارسی Français Furlan Gaelg Galego 한국어 Hawai`i Հայերեն हिन्दी Hrvatski Ido Bahasa Indonesia Íslenska Italiano עברית Basa Jawa ಕನ್ನಡ Kiswahili Kreyòl ayisyen Latina Latviešu Lëtzebuergesch Lietuvių Limburgs Lojban Magyar Македонски മലയാളം Māori मराठी Bahasa Melayu Монгол Nederlands 日本語 ‪Norsk (bokmål)‬ ‪Norsk (nynorsk)‬ Occitan O'zbek ਪੰਜਾਬੀ Plattdüütsch Polski Português Română Runa Simi Русский Shqip Sicilianu Simple English Slovenčina Slovenščina Српски / Srpski Srpskohrvatski / Српскохрватски Seeltersk Suomi Svenska ไทย Tiếng Việt Türkçe Українська 中文 Powered by MediaWiki Wikimedia Foundation This page was last modified on 5 January 2009, at 00:08. All text is available under the terms of the GNU Free Documentation License. (See Copyrights for details.) Wikipedia® is a registered trademark of the Wikimedia Foundation, Inc., a U.S. registered 501(c)(3) tax-deductible nonprofit charity. Privacy policy About Wikipedia Disclaimers if (window.runOnloadHook) runOnloadHook();
 

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