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Title: Earth Sciences/Geochemistry - Martian Geochemistry Summarizes the geochemical results obtained by NASA's Mars Pathfinder mission. Includes plots of geochemical trends, and comparisons with earlier Viking mission data as well as with Earth geochemistr |
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Stable_Isotopes_and_Mineral_Resource_Investigations An information hand-out from the US Geological Survey, introducing the topic of stable isotopes and providing some examples of their use in determining the origins of mineral deposits in the United St
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Mars Pathfinder - Science Results - Mineralogy and Geochemistry

Mars Pathfinder Science Results
The Alpha Proton X-Ray Spectrometer on the rover measured the compositions
of nine rocks. The silicon content of some of the rocks is much higher than
that of the martian meteorites, our only other samples of Mars. The martian
meteorites are all mafic and ultramafic igneous rocks, volcanic and intrusive
rocks that are relatively low in silicon and high in iron and magnesium.
Such rocks would be expected to form by partial melting of the upper mantle
of Mars. The melt rises up though the crust and solidifies at or near the
surface. The mafic volcanic martian meteorites, referred to as basalts,
are the most common rock on Earth and have also been found on the Moon.
Based on the composition of the martian meteorites and the presence of plains
and mountains that look like features produced by basaltic volcanism on
Earth, geologists expected to find primarily basalts on Mars.
The rocks analyzed by Pathfinder, however, are not basalts. If they are
volcanic as suggested by their pitted surface texture, presumably
formed when gases trapped during cooling left small holes in the rock
their silicon content classifies them as andesites. One way that andesites
can form is when a basaltic melt from the mantle intrudes deep within the
crust. Crystals rich in iron and magnesium form and are separated from the
melt, leaving a more silicon-rich melt that erupts onto the surface. The
andesites were a great surprise, but because we do not know where these
rocks came from on the martian surface, we do not know the full implications
of this discovery. If the andesites are representative of the highlands,
they suggest that ancient crust on Mars is similar in composition to continental
crust on Earth. This similiarity would be difficult to reconcile with the
very different geologic histories of the two planets. Alternatively, the
rocks could represent a minor fraction of high-silicon rocks on a predominately
basaltic plain.
Intriguingly, not all the rocks appear to be volcanic. Some have lineations
that may be layers like those in terrestrial sedimentary rocks, which form
by deposition of smaller fragments of rocks in water. Indeed, rover images
show many rounded pebbles and cobbles on the ground. In addition, some larger
rocks have what look like embedded pebbles and shiny indentations, where
it looks as though rounded pebbles that were pressed into the rock during
its formation have fallen out, leaving holes. These rocks may be conglomerates
formed by flowing liquid water. The water would have rounded the pebbles
and deposited them in a sand, silt and clay matrix; the matrix was subsequently
compressed, forming a rock, and carried to its present location by the flood.
Because conglomerates require a long time to form, if these martian rocks
are conglomerates they suggest that liquid water was once stable and that
the climate was therefore warmer and wetter than at present. A possible
alternative explanation
for the bumpy textures is weathered lithic fragments and crystals in volcanic
rocks.
Alpha Proton X-Ray Spectrometer
(APXS)
Note: The compositions plotted in the following 5 figures have been
superseded by the results presented in: Rieder,
R., et al., 1997, The chemical composition of the Martian soil and rocks
returned by the mobile Alpha Proton X-ray Spectrometer: Preliminary results
from the X-ray mode, Science, 278: 1771-1774.
hap_1.jpg (full size)
In this diagram, preliminary Pathfinder APXS analyses of soils (yellow
dots) extend the range of Viking soil analyses. The analysis of Yogi appears
to be contaminated by dust adhering to the rock's surface. The rock composition
can be estimated by subtracting a portion of dust; the resulting Yogi composition
is very similar to that of Barnacle Bill (we assumed 50% dust having the
composition of drift analysis A-5 and used a linear mixing model to subtract
the dust which is only strictly valid if the dust, where present, is thicker
than the APXS penetration depth). Barnacle Bill is also contaminated by
dust, but to a lesser extent.
hap_2.jpg (full size)
APXS analyses of Martian soils are compared with Viking soil analyses.
Each element is normalized to silicon in this diagram. The yellow boxes
representing Viking data include all analyses and their analytical uncertainties
reported by B.C. Clark and others (1982) Journal of Geophysical Research,
vol. 87, p. 10,064. Although the first APXS soil analysis (A-2) was reported
to be almost identical to Viking soils, ssubsequent analyses demonstrate
some variability and a few significant differences from Viking analyses.
Specifically, soils at the Pathfinder site generally have higher aluminum
and magnesium, and lower iron, chlorine, and sulfur. Scooby Doo, which
appears to be a sedimentary rock composed primarily of compacted soil,
also exhibits a few chemical differences form the surrounding soils. Analysis
A-5 represents a deposit of windblown dust (called drift), whereas the
other soil analyses may be cemented materials.
hap_3.jpg (full size)
This diagram (preliminary X-ray data) illustrates chemical differences
between terrestrial rocks and meteorites inferred to have been derived
from Mars. The Martian meteorites (as well as Viking soil analyses) all
plot to the left of the fields for Earth rocks. Pathfinder APXS analyses
of rocks (stars) and soils (yellow dots) appear to plot in the gap between
these previously defined fields, although they are similar to at least
one basaltic meteorite. The other two stars represent the compositions
of Barnacle Bill and Yogi. The analysis of Yogi appears to be contaminated
by dust adhering to the rock's surface. The rock composition can be estimated
by subtracting a portion of dust; the resulting Yogi composition is very
similar to that of Barnacle Bill (we have assumed 50% dust having the composition
of drift analysis A-5 and used a linear mixing model to subtract the dust
which is only strictly valid if the dust, where present, is thicker than
the APXS penetration depth). Barnacle Bill is also contaminated by dust,
but to a lesser extent.
hap_4.jpg (full size)
The Pathfinder APXS chemical analyses of Barnacle Bill and Yogi (corrected
for adhering dust) have been recast into plausible minerals using the CIPW
norm calculation. If they are fully crystalline igneous rocks, both possibly
consist of orthopyroxene (magnesium-iron silicate), feldspars (aluminum
silicates of potassium, sodium, and calcium), quartz (silicon dioxide),
and other minerals that include magnetite, ilmenite, iron sulfide, and
calcium phosphate.
hap_5.jpg (full size)
This commonly used chemical classification for lavas shows that Barnacle
Bill and Yogi (corrected for adhering dust) are distinct from basaltic
Martian meteorites (shown as red squares). The Pathfinder APXS analyses
have been corrected for the presence of a small amount of salt, and sulfur
is assumed to be present as sulfide. These rocks plot in or near the field
of andesites, a type of lava common at continental margins on the Earth.
The preliminary data for alkalis are likely to represent upper limits,
so refinement of these analyses could shift them to slightly lower Na2O
+ K2O and higher SiO2. We do not presently know whether these are igneous
(crystallized from a melt), sedimentary (grains/fragments deposited by
wind or water or precipitates), or metamorphic rocks (deformed).
The preliminary APXS results on Barnacle Bill, Yogi and soil!
Elemental Breakdown
Oxide Breakdown
Earth-Mars Comparison
Barnacle Bill Rock
Hypothesis: APXS data show composition of rock is consistent with
volcanic andesite, but rough texture of surface suggests it may be a "breccia."
Could it be composed of many different rock fragments that combine to
give a similar overall composition?
Method: Target Barnacle Bill with "multispectral spot" (all
geology filters at full spatial resolution of about 1-2 cm per picture element)
Goal: Determine variability of reflectance spectra (mineralogy) across
the face of the rock
If all spectra are similar: rock is "homogeneous" (composed
of the same material)
If spectra vary: rock may be "heterogeneous" (such as an impact
melt breccia or sedimentary conglomerate)
Result: Spectra taken from many different locations show only two
basic kinds of spectra:
Soil-like deposits
Dark rock face
Implication: At spatial resolution of 1-2 cm, rock composition is
homogeneous. However, rock may be composed of fine-grained materials (<
1-2 cm) that cannot be seen with this method.
"Barnacle Bill" up close
ss013.jpg (388K)
"Barnacle Bill" multispectral spot
ss014.jpg (78K)
This image shows the location of Barnacle Bill rock
(left of the Sojourner rover) and the approximate location of the full-resolution
"multispectral spot" acquired on Barnacle Bill. Lossless (no compression)
images were taken in all geology filters using the IMP camera to study in
detail the variation of brightness in each filter, which provides information
regarding the mineralogy of the material sampled. Spectra were extracted
from several study regions (shown to the right of the high resolution view).
The green area represents soil found behind the rock. Red patches represent
brighter areas on the rock that are interpreted as accumulations of wind-blown
dust found in small holes, or vesicles, on the rock. Blue patches represent
darker rock faces not contaminated by a soil deposit. The spectra of these
materials are shown in the accompanying figure.
Preliminary data acquired from the "multispectral
spot" image sequence for Barnacle Bill rock. Images were acquired with
no compression in all geology filters. Reflectance spectra (that is, the
variation of brightness with wavelength, or color) are shown for background
soil (green), soil-like deposits found on and within small holes in the
rock (red), and dark portions of the rock face (blue). Comparison of the
spectra of these three types of materials demonstrates that the rock has
relatively homogeneous composition at the spatial resolution of the patches
sampled (about 1-3 cm). That is, all soil-like deposit and rock face spectra
cluster in both their overall brightness (reflectance) and shape of their
reflectance curves. A more heterogeneous rock would show variable spectral
characteristics across its face. Note that the spectra of the soil-like
deposit is intermediate to that of the background soil and rock face spectra.
This is consistent with the interpretation that the soil-like deposit is
a relatively thin layer in which portions of the rock are also sampled within
the patches selected.
Also shown are laboratory spectra of oxidized and
unoxidized volcanic rocks from Earth. Scientists will compare spectra of
terrestrial materials such as these to help determine the composition of
the rocks observed at the landing site in combination with data returned
by other instruments such as the APXS.
"Flat Top" color imaging
pr1.jpg (78K)
Rover & soil - High res
pr2.jpg (47K)
Spectral strip
pr3.jpg (512K)
In the foreground of each image is "Flat Top". Each frame was
taken by the IMP camera using a different color filter. The color filters
alter the appearance of the image. The red filter has enhanced both the
textures of the rocks and the dust on the surface of "Flat Top".
The Sojourner rover has successfully navigated the rear deployment ramp.
This high resolution color image shows the front, left portion of the rover.
The micron scale soil beneath the rover was the first specimen examined
by the Alpha Proton X-Ray Spectrometer.
This image shows the Sojourner rover in its traveling configuration. The
rover has since stood up and driven onto the surface of Mars. The red rectangle
represents the location of the spectral analysis performed by the Imager
for Mars Pathfinder.
"Stripe" rock color image
stripe_3color.jpg (62K)
"Stripe" Rock: Multispectral spot
stripe_spectra.jpg (47K)
One of the first "multispectral spots"
obtained by the IMP camera was of the Stripe Rock on Sol 4. A multispectral
spot measurement obtains small images of a region of interest in all geology
filters with no image compression. Stripe rock is of interest to Mars Pathfinder
scientists because of a bright vertical stripe that appears on the center
of the rock face. It was thought that this stripe might be an intruded vein
of material of different composition than the surrounding rock.
The color image of this rock shows that the stripe
is of similar color to the surrounding soils (see arrow). A detailed examination
of the rock was conducted to extract preliminary reflectance spectra (that
is, the variation of brightness with color) from nearby bright and dark
soils, the stripe, and the surrounding rock. Although these data require
further calibration (e.g., the lower reflectance at 965 nm is not reliable
at this time), they do show that the general spectral characteristic of
the stripe is quite similar to the nearby dark soil. This suggests that
the "stripe" is actually an accumulation of soil deposited in
a crack in the rock face.
Mars Pathfinder Mission
Mineralogy and Geochemistry Science Operations Group
Return to Science Results
Directory
Mars Pathfinder Home Page
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Summarizes | the | geochemical | results | obtained | by | NASA's | Mars | Pathfinder | mission. | | Includes | plots | of | geochemical | trends, | and | comparisons | with | earlier | Viking | mission | data | as | well | as | with | Earth | geochemistr | |
http://mars.jpl.nasa.gov/MPF/science/mineralogy.html
Martian Geochemistry 2008 December
dvd rental
dvd
Summarizes the geochemical results obtained by NASA's Mars Pathfinder mission. Includes plots of geochemical trends, and comparisons with earlier Viking mission data as well as with Earth geochemistr
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